Product ID:TOLUIDINE BLUE O, T3260
MSDS Date:07/01/1999
FSC:6505
NIIN:00N092733
Status Code:A
MSDS Number: CJTNS

Emergency Phone: 314-771-5765

Info Phone: 314-771-5765

Cage: 21076

Telephone: 314-771-5765

Cage: 21076

TOLUIDINE BLUE O

CAS: 92-31-9

RTECS: SP5670000

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:SEE TOXICOLOGICAL INFORMATION.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: MAY BE HARMFUL BY INHALATION,
INGESTION, OR SKIN ABSORPTION. MAY CAUSE EYE IRRITATION. MAY CAUSE
SKIN IRRITATION. TO THE BEST OF MANUFACTURER'S KNOWLEDGE, THE
CHEMICAL, PHYSICAL, AND TOXICOLOGI CAL PROPERTIES HAVE NOT BEEN
THOROUGHLY INVESTIGATED.
Effects of Overexposure:SEE HEALTH HAZARDS.

First Aid:EYES: IMMEDIATELY FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT
LEAST 15 MINUTES. SKIN: WASH IMMEDIATELY WITH SOAP AND COPIOUS
AMOUNTS OF WATER. INHALATION: REMOVE TO FRESH AIR. IF NOT
BREATHING, GIVE AR TIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT,
GIVE OXYGEN. INGESTION: WASH OUT MOUTH WITH WATER PROVIDED PERSON
IS CONSCIOUS. CALL A PHYSICIAN. WASH CONTAMINATED CLOTHING BEFORE
REUSE.

Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL POWDER OR
APPROPRIATE FOAM.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.

Spill Release Procedures:WEAR NIOSH APPROVED RESPIRATOR, CHEMICAL
SAFETY GOGGLES, RUBBER BOOTS AND HEAVY RUBBER GLOVES. SWEEP UP,
PLACE IN A BAG AND HOLD FOR DISPOSAL. AVOID RAISING DUST. VENTILATE
AREA AND WASH SPILL SITE AF TER MATERIAL PICKUP IS COMPLETE.

Handling and Storage Precautions:AVOID INHALATION. AVOID CONTACT WITH
EYES, SKIN AND CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE. KEEP
TIGHTLY CLOSED. STORE IN A COOL DRY PLACE.

Respiratory Protection:NIOSH APPROVED RESPIRATOR.
Ventilation:MECHANICAL EXHAUST REQUIRED.
Protective Gloves:COMPATIBLE CHEMICAL-RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE
SHOWER .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
TOXICOLOGICAL INFORMATION: SEE ACTUAL ENTRY IN RTECS FOR COMPLETE
INFORMATION.

Appearance and Odor:GREEN POWDER.

STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products:TOXIC FUMES OF CARBON MONOXIDE, CARBON
DIOXIDE, NITROGEN OXIDES, HYDROGEN CHLORIDE GAS, SULFUR OXIDES.

Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE
SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL
ENVIRONMENTAL REGULATIONS.

Toxicological Information:RTECS #: SP5670000 - PHENOTHIAZIN-5-IUM,
3-AMINO-7-(DIMETHYLAMINO)-2-METHYL-, CHLORIDE. TOX DATA: IPR-RAT
LD50: 215 MG/KG; AEPPAE 204, 288, 1947. IVN-RAT LD50: 28930 UG/KG;
SMBUA9 9, 96, 1951. IVN-MUS LD50: 27560 UG/KG; SMBUA9 9, 96, 1951.
UNR-MUS LD50: 28 MG/KG; JMCMAR 17, 902, 1974. INV-RBT LD50: 13440
UG/KG; SMBUA9 9, 96, 1951. IVN-DOM LD50: 10 MG/KG; VHTODE 38, 329,
1996. TARGET ORGAN DATA: BE HAVIORAL (CONVLS/EFT ON SEIZURE
THRESHOLD); LUNGS, THORAX/RESP (RESP STIMULATION, OTHER CHANGES);
GI (NAUS/VOMIT); BLOOD (OTHER CHANGES). ONLY SELECTED REGISTRY OF
TOX EFTS OF CHEM SUBSTANCES (RTECS) DATA IS PRESENTED HERE. (SUP
DAT)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:DATA NOT YET AVAILABLE.

Transport Information:CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION
INFORMATION.

Federal Regulatory Information:REVIEWS, STANDARDS, AND REGULATIONS: OEL
= MAK. NOHS 1974: HZD A1164; NIS 3; TNF 224; NOS 4; TNE 1226. NOES
1983: HZD A1164; NIS 1; TNF 196; NOS 4; TNE 7956; TFE 5824. EPA
GENETOX PROGRAM 1988, INCONC LUSIVE: B SUBTILIS REC ASSAY; S
CEREVISIAE GENE CONVERSION. EPA TSCA SECTION 8 (B) CHEMICAL
INVENTORY.
State Regulatory Information: